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Investigation of Hydrologic and Biogeochemical Controls on Arsenic Mobilization Using Distributed Sensing at a Field Site in Munshiganj, Bangladesh Nithya Ramanathan Sarah Rothenberg, UCLA Department of Statistics D Estrin T C. Harmon Charles Harvey J A. Jay Eddie Kohler
ABSTRACT: The presence of arsenic in the groundwater has led to the largest environmental poisoning in history; tens of
millions of people in the Ganges Delta continue to drink groundwater that is dangerously contaminated with
arsenic. A current working hypothesis is that arsenic is mobilized in the near surface environment where
sediments are weathered by seasonal changes in the redox state that drive a cycle of pyrite oxidation and iron oxide reduction. In order to test the supporting hypothesis that subsurface geochemical changes may be
induced by agricultural activity, we deployed 42 wirelessly networked ion-selective electrodes, including
calcium, ammonium, nitrate, ORP, chloride, carbonate, and pH in a rice paddy in the Munshiganj district of
Bangladesh in January of 2006. Each sensor was connected to an MDA300 sensor board and Mica2 wireless
transceiver and computational device. Over a period of 11 days, we observed clear diel, and diurnal trends in 4 of the electrodes (calcium, ammonium, chloride and carbonate). The trends may be due to hydrological
changes, or geochemical changes induced either by photosynthesis in the overlying water (which then
infiltrated to the depth of the sensors) or in the root zone of rice plants.
While the spatiotemporally dense measurements from wireless sensor networks enable scientists to ask new
questions and elucidate complex relationships in heterogeneous physical environments such as soil, there are many practical issues to address in order to collect data usable for scientific purposes. For example, in
response to a stream of faults in one of our sensor network deployments, we designed Sympathy to enable
users to find and fix problems impacting the quantity of data collected in the field. Sympathy detects packet
loss experienced at the base station and systematically assigns blame to faulty components in the network
for remediation, replacing the prior policy of ad-hoc node rebooting and battery replacements. Sympathy has
been deployed in many habitat monitoring sensor networks.
While using Sympathy at our Bangladesh field site we received 80% of the sensor data expected at the base
station, upon returning, post-deployment analysis revealed that 42% of these sensor data were potentially
faulty. Due to the remote location of the deployment, we were unable to go back and validate the questionable
segments of the data set, forcing us to discard potentially interesting information. In addition to being
undesirable, this response is often avoidable as well. Even simple actions such as checking sensor
connections and quickly validating sensors in the field could have increased our confidence in the quality of the data, minimizing doubts that data observations were simply caused by badly behaving hardware. To improve
data quality, we have designed a system called Confidence, which continuously monitors data collected at a
base-station to identify faulty data and notify the user in the field of actions they can take to validate the data
or remediate the sensor fault. Augmenting a sensor network deployment with Confidence and Sympathy
enables users in the identification and remediation of faults impacting the quality and quantity of data
respectively.
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