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Implications for Neoarchaean ocean chemistry from primary carbonate mineralogy of the Campbellrand-Malmani Platform, South Africa Dawn Y. Sumner, University of California, Davis J P. Grotzinger
ABSTRACT: The precipitation of calcite and aragonite as encrustations directly
on the seafloor was an important platform-building process during deposition of
the 2560-2520 Ma Campbellrand-Malmani carbonate platform, South Africa.
Aragonite fans and fibrous coatings are common in unrestricted, shallow
subtidal to intertidal facies. They are also present in restricted facies, but
are absent from deep subtidal facies. Decimetre-thick fibrous calcite
encrustations are present to abundant in all depositional environments except
the deepest slope and basinal facies. The proportion of the rock composed of
carbonate that precipitated as encrustations or in primary voids ranges from 0%
to > 65% depending on the facies. Subtidal facies commonly contain 20-35%in
situ precipitated carbonate, demonstrating that Neoarchaean sea water was
supersaturated with respect to aragonite, carbonate crystal growth rates were
rapid compared with sediment influx rates, and the dynamics of carbonate
precipitation were different from those in younger carbonate platforms. The
abundance of aragonite pseudomorphs suggests that sea-water pH was neutral to
alkaline, whereas the paucity of micrite suggests the presence of inhibitors to
calcite and aragonite nucleation in the mixed zone of the oceans.
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